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More in Catalysis

Voltage-Driven Blisters Give 2D Nanochannels Their Ionic Memory

Real-time imaging reveals how tiny structural changes inside layered nanochannels track shifts in ionic current and device behavior. A recent study in the journal Nature Materials reveals the mechanical origin of ionic memory in two-dimensional (2D) nanochannels. By combining optical imaging with electrical measurements, the researchers demonstrate that sufficiently large applied voltages can trigger the formation or enlargement of liquid-filled blisters that alter channel geometry and ion transport. The results establish electromechanical coupling as a mechanism for ionic memory in the devices studied and offer new strategies for developing reliable nanofluidic memristors for ion-based information processing. Some studies have suggested that ion pairing or polyelectrolyte formation could drive memory effects in channels assembled from layered materials. But researchers have lacked…

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More in Nanomaterials & 2D Materials
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Tiny groups of atoms could make green hydrogen use less precious metal

A new hydrogen-producing catalyst matched the performance of a commercial platinum catalyst while using 75% less precious metal in tests. The design places just a few ruthenium atoms together so that more of the valuable material can participate in the reaction. The work could help lower one of the costs of producing green hydrogen, which uses renewable electricity to split water. It also shows why spreading metal atoms as far apart as possible is not always the best approach. Researchers led by the Korea Advanced Institute of Science and Technology described the catalyst in Nature Communications. The results come from experimental water-electrolysis equipment, with larger-scale and longer-term validation still needed before commercial savings can be established. Electrolysis separates water into hydrogen and oxygen. Catalysts help the reactions proceed efficiently, but the…

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More in Hydrogen & Fuel Cells