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Synthesis, Functionalization, and Properties of 3-Aminosydnones: A Forgotten Class of Mesoionic Heterocycles
3+ hour, 30+ min ago (430+ words) Chemistry Views Fr'd'ric Taran, SCBM " Universit' Paris Saclay, Gif-sur-Yvette, France, and colleagues have renewed attention to a long-overlooked class of mesoionic heterocycles: 3-aminosydnones. The team developed a scalable synthesis of a key 3aminosydnone building block bearing an exocyclic NH" group and…...
Tellurium-Templated Assembly Opens New Pathways in Polyoxoniobate Chemistry
3+ mon, 2+ week ago (333+ words) Chemistry Views Polyoxometalates (POMs) are valued for their remarkable structural diversity, nanoscale dimensions, and rich redox chemistry. Their niobium-based relatives, polyoxoniobates (PONbs), are more difficult to synthesize. Yet these materials are particularly attractive because of their high stability and strong…...
New Global Headquarters of IUPAC in Spain and Italy
3+ mon, 2+ week ago (250+ words) Chemistry Views M'laga in Spain and Rome in Italy will share the new global headquarters of the International Union of Pure and Applied Chemistry (IUPAC). The IUPAC Secretariat, serving as the administrative and technical center of the Union, is relocating…...
How Single Metal Atoms Improve Hybrid Water Electrolysis
3+ mon, 3+ week ago (267+ words) Chemistry Views Soressa Abera Chala and Carsten Streb, Johannes Gutenberg University Mainz, Germany, Bing Joe Hwang, National Taiwan University of Science and Technology, Taipei, Taiwan and National Synchrotron Radiation Research Center (NSRRC), Hsinchu, Taiwan, and colleagues have developed a hybrid…...
-Coupled J-Aggregates Enable Stable NIR-II Imaging and Multimodal Cancer Ther
3+ mon, 3+ week ago (178+ words) Chemistry Views HCY-3 was designed as a hemicyanine dye (HCY) with hydroxyl donor groups to promote hydrogen bonding. Comparisons with structural variants (S-HCY-1, HCY-4, and HCY-9) confirmed that molecular planarity and donoracceptor alignment are critical for J-aggregation (the ordered head-to-tail…...
Hyperpyramidalized Alkenes As Synthetic Building Blocks
3+ mon, 4+ week ago (150+ words) Neil K. Garg, University of California, Los Angeles, USA, and colleagues have used highly strained alkenes'cubene and 1, 7-quadricyclene'to provide a straightforward way to build highly complex, three-dimensional molecules of interest to medicinal chemists. Alkene carbons are typically trigonal planar, as in…...
Triplet Up-Converted Anti-Kasha Phosphorescence at Room Temperature in Dendrimer Materials
4+ mon, 4+ hour ago (410+ words) Chemistry Views High-lying triplet emission generally follows two pathways: - Independent T" emission: The high-lying triplet state (T") emits without relying on T" (low-lying triplet state), requiring a large energy gap between T" and T" and a radiative transition rate of…...
Carbon-Coated Copper Catalysts for Pyridine Synthesis
4+ mon, 3+ day ago (671+ words) Chemistry Views Sergey V. Kolotilov, National Academy of Sciences of Ukraine, Kyiv, Ukraine, and his colleagues wanted to understand how copper and carbon components contribute to the catalytic synthesis of fused pyridines. The central challenge was to determine whether Cu is…...
New President of the Italian Chemical Society (SCI)
4+ mon, 3+ day ago (320+ words) Author: Vera Koester Author Archive: Vera Koester A long'standing figure in the national chemical community, Mondello has held multiple leadership roles within SCI, including President of the Division of Analytical Chemistry (20222024) and Vice President of the same division (20192021). His presidency…...
Excited States Make Common Nitroarenes Powerful Photocatalysts
4+ mon, 4+ day ago (69+ words) Chemistry Views Enrique M. Arpa, Daniele Leonori, and colleagues, RWTH Aachen University, Germany, have explored how simple nitroarene molecules can act as light-driven catalysts, transferring energy to other molecules without needing high-energy UV light. The team says that this provides a…...